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(B6, especially in the pyridoxine form, is one of the few B vitamins that can lead to toxicity when used in excess.) Threonine is also important to gut barrier integrity in the small intestine, and I have read some reports of it helping with minimizing reactions to gluten, although I have not studied this in great depth yet
It can indicate bacterial contamination or that the peptide has degraded and precipitated out of the solution
Once the vial is used or opened when you first use it, you should continue refrigerating them after use
Always follow the package leaflet when available
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